we might imagine that crown glass would be the best material for photographic lenses. This however is not the case. The least dispersive lenses intercept the greatest number of chemical rays, and therefore those of crown glass, and consequently achromatic lenses, cannot be advantageously employed for photographic purposes.
We are apt to think that when lenses are optically perfect they ought be so chemically. This remark was made in 1840, when many excellent daguerreotypes were made, by the use of the ordinary spectacle lens. But at that time our material sensitive to light was iodide of silver only. Iodide of silver is affected very little by other rays than the indigo. The image of the sun from an uncorrected lens on iodide of silver is extremely sharp. When collodian, therefore, is prepared with only an iodide, it is not essential that the camera lens be carefully achromatic. The bromide of silver is, however, decomposed in a larger part of the spectrum, and with it, it is important to work with corrected lenses.